The first non-Spanish European who tried to climb the mountain was Alexander von Humboldt in 1802; however, he only reached a height of about 4,500 m (14,760 ft). In 1858 Moritz Wagner investigated the mountain, but he could not reach the summit either.
On November 28, 1872, German geologist Wilhelm Reiss and his Colombian partner, Angel Escobar, finally reached the summit of Cotopaxi.
In 1873 it was summitted by German Geologist Moritz Alphons Stübel and four Ecuadorians, Rafael Jantui, Melchor Páez, Vicente Ramón and Eusebio Rodriguez.
In 1880 British mountaineer Edward Whymper and the Italian guides Jean-Antoine Carrel and Louis Carrel made the third recorded ascent of Cotopaxi and spent a night on the summit.
Painters Rudolf Reschreiter and Hans Meyer reached the summit in 1903, and many of Reschreiter’s paintings feature a view of Cotopaxi.
In the late 20th century, summiting Cotopaxi became a major tourist draw. The José F. Ribas Refuge (Refugio José Félix Ribas) was built in 1971 at an elevation of 4,864 m (15,960 ft) and enlarged in 2005.
A tragedy occurred on Easter Sunday 1996 when an avalanche partially buried the Refuge and dozens of tourists. The glacier above the Refuge was probably weakened by an earthquake that had shaken the entire Province of Cotopaxi for several days prior to the avalanche. In the warm midday sun a huge portion of the ice wall broke loose. Being Easter, there were many day visitors on the mountain who were buried in the ice and snow. Those trapped in the Refuge broke windows on the downhill side to climb to safety, but 13 people died on the slope above. The Refuge itself is located in a valley and consequently vulnerable to future avalanches.